The widespread Late Paleozoic-Early Mesozoic magmatism in the Eastern Tianshan provides critical insights into geodynamic evolution of the southern Altaids. In this study, we conduct an integrated study of field geology, petrology, U-Pb zircon geochronology and major-trace elemental and Sr–Nd–Hf isotopic geochemistry on the Late Carboniferous monzogranite and diorite dyke and the Late Triassic gabbroic diorite dyke in the central part of the Eastern Tianshan. Geochronological data indicate that the monzogranite, diorite dyke and gabbroic diorite dyke formed at ∼318 Ma, ∼317 Ma and ∼235 Ma, respectively. The Late Carboniferous monzogranite shows transitional characteristics between highly fractionated and A-type granites, with relatively high zircon saturation temperatures (800–836 °C). It was derived by partial melting of juvenile infracrustal rocks, followed by plagioclase-dominated fractional crystallization. The Late Carboniferous diorite dyke has high Al2O3 contents (mostly >17 wt%) and Ba/La ratios, indicating an origin from a hydrous lithospheric mantle source that had been metasomatized by slab-derived fluids. The Late Triassic gabbroic diorite dyke, with relatively high Mg# values (57–58) and Th contents (3.28–3.46 ppm), originated from a less hydrous lithospheric mantle source containing significant sediment-derived components. Our new results, combined with previous studies, reveal an end-Early Carboniferous to middle Late Carboniferous magmatic flare-up in the Dananhu arc. The magmatic flare-up occurred in a long E-W trending banded zone parallel to the strike of the arc and was accompanied by significant normal arc magmatism, which widely migrated to the south of the Dananhu arc in comparison to prior magmatism. These together with coeval extension-related volcanic, sedimentary, structural and metamorphic events in the Dananhu and adjacent areas were attributed to southward rollback of the subducted Kanguer oceanic slab. The long-time arc magmatism and regional crustal thickening before the Late Triassic led to the formation of an arclogite-bearing root beneath the Dananhu arc. The Late Triassic extension-related magmatism in the Dananhu arc, which was synchronous with or slightly younger than regional thickened crust-derived magmatism, was linked to the local root foundering of the long-lived Dananhu arc at the late stage of orogenesis. The episodic occurrence of geodynamic processes such as slab rollback, arc root foundering and ridge subduction/slab tearing, which were accompanied by massive input of juvenile materials into continental crust, contributed to multi-stage significant crustal growth in southern Altaids.

Subduction process plays an important role in triggering chemical metasomatism of the lithospheric mantle beneath orogenic belts. The lithospheric mantle beneath the West Qinling orogen is extensively heterogeneous, but the lithospheric modification process and related metasomatic agents remain poorly constrained. In this paper, we report in-situ elemental and isotopic compositions of minerals in mantle xenoliths from the West Qinling orogen. The mantle xenoliths are lherzolites and can be categorized into two types. Lherzolite with refractory compositions represents the residue of lithospheric mantle that have undergone high degrees of melt extraction. In contrast, lherzolites with fertile compositions contain clinopyroxenes variably enriched in incompatible elements and radiogenic Sr isotopes. These fertile lherzolites represent lithospheric mantle modified by metasomatic process in different degrees. High (La/Yb)N, Ca/Al, Nb/Ta, Nd/Yb, 87Sr/86Sr ratios and low Ti/Eu ratios of the clinopyroxenes suggest the metasomatic agent was dominated by carbonate-rich melts. This inference is supported by the identification of carbonate inclusion, reaction structures, and clinopyroxene chemical zoning in the lherzolites. Considering the tectonic background of the West Qinling orogen, the orogenic lithospheric mantle would have been metasomatized by carbonate-rich melts derived from partial melting of subducted carbonate-bearing Paleo-Tethyan oceanic slab. In this regard, petrological observations, along with in-situ elemental and Sr isotopic compositions of clinopyroxenes in mantle xenoliths can be powerful means to identify carbonate metasomatism and constrain the evolution of the lithospheric mantle beneath orogenic belts.

Late Ediacaran to Cambrian metagranitoids from the northern Veporic unit of the Western Carpathians show imprints of three metamorphic events, which can be assigned to the Cenerian, Variscan, and Alpine orogenies based on electron microprobe dating of monazite. Metamorphic monazites in the metagranitoids are mostly of the Lower to Middle Ordovician age (480–460 Ma). The Ordovician monazite formed in equilibrium with the metamorphic assemblage garnet, biotite, kyanite, ilmenite and quartz at P-T conditions of 6–7 kbar and 550–570 °C, thus providing clear evidence for Cenerian metamorphism in the Western Carpathians. Variscan metamorphism caused minor monazite growth/recrystallization at 364 ± 13 Ma and produced a new mineral assemblage garnet, kyanite, rutile and phengite at P-T conditions of 20–22 kbar and 670–690 °C. The low-grade Alpine metamorphism is recorded by monazite of Cretaceous age (96 ± 23 Ma), but only in orthogneiss of extremely low-Ca composition.The Veporic metagranitoids show incomplete transformation from magmatic stage, still preserving remnants of plagioclase, K-feldspar and high-Ti biotite. This indicates that the metagranitoids remained relatively dry and failed to complete metamorphic reactions due to kinetic factors at fluid-deficient conditions. Nevertheless, the metagranitoids likely underwent significant geochemical changes during their metamorphic evolution including a severe loss of CaO and Na2O.

We present here the first regional set of Sr-Nd-Pb isotopic compositions, major and trace element compositions and KAr ages for a representative suite of back-arc samples of the Sredinny Range (SR) of Kamchatka. Together with previously published analyses, this unique dataset allowed us to trace the source heterogeneity and invoke new mechanisms to explain the variably enriched geochemical signatures. Our results indicate that the Sr isotopic ratios and the LILE content of the studied rocks were mainly influenced by the subduction fluid. Neodymium isotopes, as well as the HFSE and REE distributions in the rocks, require a more complex explanation, depending on the geographical location of the studied samples and the age of their eruption. Melts representing Miocene rocks of the northern part of the SR and most of the rocks from the eastern and central flanks of the SR (from Miocene until present) were produced from a depleted MORB-like metasomatized mantle, and were then exposed to varying degrees of crustal assimilation and fractional crystallization. Higher HFSE contents and lower 143Nd/144Nd ratios in the western flank lavas, as well as high HFSE contents in the Quaternary lavas of the northern part of the SR and some of the lavas from the eastern flank of the southern part of the SR, require an alternative source for their enrichment. Delamination of the lithosphere explains the unusual, enriched signature of these rocks, whereas their variably enriched neodymium isotope ratios identify the various ages of the separation of the lithosphere from the mantle. The Nd isotopic composition of the rocks together with their HFSE content, therefore, serves as an unusual tracer for the enriched mantle domain, showing the presence of the older lithospheric blocks and indicating the timeframes for this source involvement in magma generation.

The Early Cretaceous peralkaline Baerzhe pluton hosts a potentially large REE-Nb-Zr-Be deposit in inner Mongolia, northeastern China. The mechanism responsible for the extreme enrichment of rare metals and rare earth elements in the pluton is still ambiguous. This study presents new evidence for silicate melt immiscibility as the key mechanism at Baerzhe using amphibole-group minerals from spherulite granite, which contains spherulites with abundant REE- and HFSE-bearing minerals. The spherulite from the transsolvus granite is composed of two distinct zones, i.e., a dark-colored core consisting of arfvedsonite aggregates and a light-colored rim consisting mostly of quartz and feldspar, rare amphibole, and abundant HFSE- and REE-bearing minerals. Four types of amphibole (AmpI, Amp-IIa, Amp-IIb and Amp-III) from the transsolvus granite and one type (Amp-IV) from the subsolvus granite are recognized, and all of them are magmatic fluoro-arfvedsonite. The earliest phase consists of euhedral inclusions of Amp-I within quartz or feldspar. They show an enrichment in HREEs relative to LREEs and a depletion in medium REEs, consistent with the REE pattern controlled by the mineral lattice. This implies that Amp-I likely formed in an initial homogeneous mel relatively depleted in REEs; thus, the mineral structure played a dominant role in REE partitioning. Compared with other types of amphiboles, Amp-IIa and Amp-IIb from the spherulite phase display the highest REE contents, with flat LREEs and MREEs and a slight upward HREE pattern. Combined with the significant accumulation of REE- and HFSE-bearing minerals in the rim zone, differences in REE patterns among different amphibole types imply that the spherulite crystallized in a volatile-rich silicate melt and was probably the product of silicate melt immiscibility. Interstitial Amp-III with lower REE contents from the matrix phase crystallized in the separate volatile-poor silicate melt. The Amp-IV from the subsolvus granite has the lowest CaO content, with strong depletion in LREEs relative to HREEs, suggesting a more evolved melt composition. It is concluded that silicate melt immiscibility may serve as an important key mechanism that occurred in the early stage of magmatic evolution, resulting in the enrichment of REEs and HFSEs, which played a critical role in the formation of large to giant ore deposits such as the Baerzhe deposit.

The intrinsic assumption of radiogenic isotope tracing is that isotope systems maintain equilibrium between melt and source. However, this assumption is not naturally correct, particularly for S-type granites, which are formed by partial melting of metasedimentary rocks. The S-type metagranites from the North Qinling Terrane show various degrees of HfNd isotope decoupling and discrepancies between whole-rock and zircon Hf isotopes. Zircon UPb dating yields emplacement ages from 946 to 890 Ma. Their high δ18O values, (87Sr/86Sr)i ratios, and negative εNd(t) values overlapped with metasedimentary rocks in the Qinling Group imply that they are derived from partial melting of the Qinling Group. The low Rb/Ba, Rb/Sr, Al2O3/TiO2, and high CaO/Na2O ratios indicate that their sources are metagraywackes. The negative correlation between decoupling degrees of HfNd isotopes and Zr concentrations suggests that the incomplete dissolution of zircon during partial melting results in the decoupling. The discrepancy between whole-rock and zircon Hf isotopes can be attributed to the combined effect of incomplete dissolution of zircons and the release of various Hf isotope compositions from partly dissolved inherited zircons to local melts. The compiled literature data suggest that whole-rock HfNd isotope decoupling of most metagraywacke-derived S-type granites is caused by incomplete melting of zircons, whereas those of metapelite-derived S-type granites may be controlled by both incomplete melting of zircons and source inheritance.

Syn- to post-collisional mafic igneous rocks are widely distributed along continental collision orogenic belts and can be used to constrain the nature of the orogenic mantle and relevant chemical geodynamic processes during orogenesis. However, there is uncertainty about the mechanisms of recycling of continental crustal materials in continental subduction channels. We report chronological and geochemical data for syn- and post-collisional mafic dikes from the East Kunlun Orogenic Belt (EKOB), western China, which provide insights into the processes of geochemical transfer and geodynamic evolution of this fossil orogen. Zircon UPb dating of the mafic dikes yields ages of 433 Ma and 409–407 Ma, corresponding to syn- and post-collisional magmatism, respectively. The rocks exhibit typical arc-like trace-element characteristics and weakly enriched Sr–Nd–Hf isotopic compositions, as well as variable zircon O isotopic compositions. These geochemical characteristics are comparable to those of Neoproterozoic paragneiss influenced by Early Paleozoic metamorphism associated with high–ultrahigh-pressure eclogitization in the EKOB and indicate that paragneiss-derived hydrous melts were likely involved in the mantle source of the studied mafic igneous rocks during continental collision. This qualitative interpretation is supported by quantitative modeling of the geochemical transfer in the continental subduction zone. We propose that the syn-collisional mafic igneous rocks were formed during the continental collision between Central Kunlun and South Kunlun Belts, whereas the post-collisional mafic igneous rocks formed in an extensional regime associated with orogenic lithosphere thinning and asthenospheric upwelling.